Please reload

Recent Posts

I'm busy working on my blog posts. Watch this space!

Please reload

Featured Posts

How to recognize carbocation rearrangements?

March 28, 2019

 

In organic chemistry, when students learn reactions oftentimes hydride and alkyl shifts happen that student might not recognize. Here are the ways to be aware of them:

1. Any reactions that go through a carbocation are capable of rearrangements such as SN1, E1, and alkene reactions with acids.

2. Rearrangements happen at the carbocation stage. 

3. The shift happens if the neighboring carbon would make for a more stable, more substituted carbocation. For example if a secondary carbocation is located next to a carbon that is tertiary, rearrangement will take place.

4. If the hydrogen is present, do hydride shift. If there are only carbons, do an alkyl shift.

5. Often, the professor asks students for mechanism and gives reactant and product. Looking at the product if it's structure has changed from that of the reactant, rearrangement took place. For example, if you see a cyclopentane expanding to a cyclohexane, or a ring becoming smaller, then a rearrangement definitely took place. 

 

At Transformation Tutoring, we hope these tips help our students understand rearrangements better in organic chemistry. Our incredible general and organic chemistry tutors are ready to help you in your chemistry classes. Call today 646-407-9078 to schedule your session. 

Please reload

Follow Us