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Consider the following two equilibria and their respective equilibrium constants:(1) NO(g) + 1/2 O₂(g) ⇌ NO₂(g) (2) 2 NO₂(g) ⇌ 2 NO(g) + O₂(g)Which one of the following is the correct relationshi

  • May 4
  • 1 min read

Consider the following two equilibria and their respective equilibrium constants:

(1) NO(g) + 1/2 O₂(g) ⇌ NO₂(g) (2) 2 NO₂(g) ⇌ 2 NO(g) + O₂(g)

Which one of the following is the correct relationship between the equilibrium constants K₁ and K₂?

A) K₂ = –K₁/2

B) K₂ = 1/(2K₁)

C) K₂ = 1/(2K₁)²

D) K₂ = 2/K₁

E) K₂ = (1/K₁)²


Solution:

What do we need to do to equation 1 to turn it into equation 2. Let's look at NO. To go to the second equation, we need to multiply NO by 2 and reverse the equation. That means we need to square K1 and take reciprocal of that.

E is the correct answer.



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