Chapter 7: Haloalkanes, Halogenation, and Radical Reactions
Table of contents of main topics:
1. Preparation of Haloalkanes by Halogenation Of Alkanes
Reagent: Br2, light.
Product: Adds Br to the most substituted carbon on the alkane
Mechanism
Radicals contain at least one unpaired electron. The arrows that we draw for
radical reaction mechanisms are different from regular arrows.
Radical reactions generally have 3 steps in their mechanism:
Initiation (making a radical)
Propagation (making the desired product)
Termination (getting rid of all the radicals)
In the mechanism, the first step is initiation. The bond between Br-Br breaks to give us two Br radicals.
Propagation is made up of 2 steps. First, we draw the alkane starting material. Bond between hydrogen and carbon breaks (on the carbon we want to attach Br to) and bromine radical forms a bond with hydrogen, resulting in HBr and alkane radical. In the second step, alkane radical reacts with Br-Br. The bond between Br-Br breaks and the alkane radical forms a bond with the bromine to give the desired product.
Termination is used to get rid of any radical created in the reaction. During termination any radicals created in the reaction come together and make a bond.
