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What is the oxidation number of Mo in MoO4^2-?

(A) +2 (B) +4 (C) +6 (D) +8


Solution: Let's first go over some rules for determining the oxidation number.

Rules for determining oxidation numbers:

  • Free, neutral elements have an oxidation number of 0.

  • Group 1 metals have an oxidation number of +1 (can be found on the Periodic Table)

  • Group 2 metals have an oxidation number of +2

  • Oxygen is -2 in all compounds other than peroxide (H2O2)

  • Hydrogen is +1 unless it is bonded to a metal

  • The sum of oxidation numbers in a neutral molecule is 0

  • The sum of oxidation numbers in a charged molecule (ion) is equal to the charge

Now, we can look at our molecule MoO4^2-

Let's say the oxidation number of Mo is X.

The overall charge of the molecule is 2-. The oxidation number of oxygen is -2.

Putting it all together, we can make an equation X+ (4*-2)=-2

X-8= -2

X = +6 (C)


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